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STANDARD SPECIFICATIONS FOR PERMANENT MAGNET MATERIALS 2015-05-12
SECTION I 1.0 SCOPE & OBJECTIVE 1.1 Scope: This standard defines magnetic, thermal, physical and mechanical characteristics and properties of commercially available permanent magnet materials as listed in Table 1. There are a large number of permanent magnet materials in use which are not described in this document. These materials generally fall into one of the following categories: (a) Older materials that have been largely replaced by new materials. (b) Materials made by only one company with a specialized and limited use. (c) Materials evolving. from development status to production which at this time are not mature from a commercial viewpoint. For reference purposes, the principal magnetic properties of the materials in the above categories are listed in Appendix A. 1.2 Objective: The objective of this standard is to establish criteria by which users of permanent magnet materials may be assured of magnets manufactured to present commercial standards. 2.0 DEFINITIONS & TERMS 2.1 Definitions: The following definitions characterize materials covered in this standard: 2.1.1 Permanent Magnet (Magnetically Hard) Material: A permanent magnet material, also designated as a magnetically hard material, has a coercive force gener-ally greater than 120 Oe. 2.1.2 Individual Magnet: The term individual magnet denotes a magnet purchased in a size and shape to be ready for direct incorporation into a magnetic circuit. 2.1.3 Bulk Magnet Material: The term bulk magnet material designates bar, rod, slab, strip, sheet, etc., from which the purchaser cuts, stamps or forms individual magnets. 2.1.4 Polarity of a Magnetized Magnet: The North Pole of a magnet is that pole which is attracted to the geographic North Pole. Therefore, the North Pole of a magnet will repel the north seeking pole of a magnetic compass. 2.1.5 Demagnetized Magnet: For the purposes of this standard, a magnet shall be considered demagnetized if, when any of its poles is dipped in soft iron powder (of -5, + 10 mesh), not more than 3 particles of powder adhere to it anywhere upon withdrawal. 2.2 Terms: A glossary of terms commonly used with permanent magnetic materials is given in Appendix B. 3.0 CONDITION Unless otherwise specified, bulk magnet materials shall be furnished in the non heat-treated condition, as rolled, as forged, or as-cast condition as applicable. Individual magnets shall be furnished in a fully heat-treated and demagnetized condition. 4.0 CLASSIFICATION & DESIGNATION 4.1 Classification: The classification of permanent magnet materials covered by this standard is given in Table 1. Section numbers for the material classes covered in this standard as well as reference to the International Electrochemical Commission (IEC) material code numbers are also given in the table. TABLE 1 MATERIAL CLASSIFICATION Material MMPA Section IEC Code Alnico Ceramic Rare-Earth Iron-Chromium-Cobalt II III IV V R1 S1 R4, R5 R2 4.2 Designation: Permanent magnet materials in this specification will be divided into separate sections by the MMPA Class. Each standard section will address the relevant properties, characteristics and specifications of each class of materials and the established sub-grades. In general, reference will be made to historically recognized subgrade descriptions (such as Alnico 1,2, etc., or Ceramic 5, 8, etc.) and to a system, referred to as the Brief Designation, that classifies each subgrade by typical normal energy product and typical intrinsic coercive force. In this system, for example, a material having maximum normal energy product of 5.0 megagaussoersteds (MGO) and an intrinsic coercive force of 2000 oersteds (2.0 kOe) would be assigned a Brief Designa – tion of 5.01/2.0. When similar grades exist the nearest IEC Grade Code Number will also be listed for cross reference. 5.0 MAGNETIC PROPERTIES, THERMAL PROPERTIES & OTHER CHARACTERISTICS The magnetic, thermal, surface and internal structure, and other physical characteristics are set forth in tables in each section for the different classes of magnetic 3 materials. The figures in these tables are intended to be descriptions of each of the materials. The properties of the materials produced by individual manufacturers may differ somewhat from those shown. For information concerning properties of actual grades produced, refer to individual manufacturer’s literature. The properties shown in the tables with each class shall not be used as inspection criteria of either individual magnets or bulk magnet materials. 5.1 Principal Magnetic Properties: Permanent magnet materials are identified by the following principal magnetic properties: Maximum value of energy product (BH)max MGO Residual induction Br gauss Coercive force Hc oersteds The measurement of the principal magnetic properties are made in a in closed magnetic circuit permeameter by commonly accepted procedures such as given in IEC Standard Publication 404-5 “Methods of Measurement of Magnetic Properties of Magnetically Hard (Permanent Magnet) Materials or the “MMPA Permanent Magnet Guidelines†(current edition).They are accurate only for magnets having a straight magnet axis and produced with a constant cross section along the axis of magnetization. The minimum magnet volume of a sample used to measure these magnet properties shall be one cubic centimeter and the smallest dimension shall be at least 5mm. The’ performance of a permanent magnet circuit is de-pendent on the dimensions of all components and the properties of the other components of the circuit, as well as the properties of the permanent magnet. It is recommended not to use unit properties of a material as the specification. These are generally recommended to be only used on prints or drawings to show a subgrade within a material group. Section 8.0 of the specification describes the proper means of specifying the acceptable properties of a permanent magnet component part. 5.2 Thermal Properties: Predicting magnet performance as a function of the magnet’s temperature requires knowledge of the following thermal properties: Reversible temperature coefficient of the residual induction TC (Br) %/ºC Reversible temperature coefficient of the intrinsic coercive force TC (Hci) %/ºC Curie temperature Tc ºC Maximum service temperature T max ºC The values listed for each class of materials for thermal properties are typical values intended as design guidelines only and are not to be used as a basis for acceptance or rejection. Values for irreversible temperature characteristics are not listed because they depend on the magnet material, geometry and circuit in which the magnet is used. 5.3 Surface and Internal Structure Characteristics: Permanent magnet materials have been developed primarily for their magnetic properties. The magnetic properties of some materials are produced using manufacturing techniques which are not consistent with pro-ducking perfect physical specimens. Minor physical imperfections rarely impair the magnetic capabilities of a magnet or compromise its stability or ability to resist demagnetization. Imperfections commonly found in permanent magnet materials shall be judged acceptable if the following conditions are met: (I) The magnet meets the magnetic performance criteria agreed upon between the magnet manufacturer and customer. (2) The imperfections do not create loose particles that would interfere with proper assembly or functioning in the end use device. Unless otherwise agreed, visual imperfection guidelines listed in the individual material sections apply. 5.4 Other Physical Properties: Typical values for other physical properties important to a magnet user are listed in the tables in the sections for each class of permanent magnet material and are intended to be descrimptions of the material, not criteria for acceptance or rejection. 6.0 MECHANICAL CHARACTERISTICS Most permanent magnet materials lack ductility and are inherently brittle. Such materials should not be utilized as structural components in a circuit. Measurement of properties such as hardness and tensile strength are not feasible on commercial materials with these inherent characteristics. Therefore, specifications of these properties are not acceptable. Measurements of mechanical properties shown in the tables were performed under very carefully controlled laboratory conditions. The values are shown only for reference and comparison to other classes of materials. 7.0 DIMENSIONS AND TOLERANCES Dimensions and tolerances shall be as specified on the magnet drawing and must be agreed upon between the magnet manufacturer and user before an order is accepted. Normally the magnet user furnishes a drawing to the manufacturer showing all dimensions and tolerances. When no drawing is available from the user, the manufacturer may furnish a drawing to the user for his approval before manufacturing parts. The standard for drawing, drawing notation and tolerancing is that established in ANSI Y 14.5. Although individual manufacturers will each have their own capability to hold a given tolerance, standard tolerance tables applying to specific classes of these materials are listed in the individual sections. 4 8.0 PROCESS CONTROL Most manufacturers use statistical process control to monitor key parameters at each process step. 9.0 INSPECTION &TESTING Unless otherwise agreed upon, magnets will be inspected for all specified characteristics by the use of a statistically valid sampling plan. Such plans may be derived from, Quality Planning And Analysis: From Product Development Through Use, J.M. Juran and F. M. Gryna, 3rd Edition, McGraw Hill (1993), Chapter 19. ISBN 0-07-033183-9 9.1 Performance Testing Approach--Magnetic Characteristics: The principal characteristics--Br, Hc, Hci, and (BH)max of a magnetic material are used to identify a specific subgrade within a material class. Generally, individual manufacturers can hold unit magnetic property tolerances of ± 5% for residual flux density, Br and ± 8% for coercive force, Hc. The range for the energy product, (BH)max is ± 10%. Intrinsic coercive force, Hci, is generally specified as minimum value only. The size and/or shape of the actual magnet to be produced may cause magnets to have propertie considerably different from these characteristics. Therefore, use of these characteristics in specifying acceptable properties for a given magnet shape is not recommended.The recommended means is to specify the minimum magnetic lines of flux at one or more load lines on the major or minor hysteresis loop. A magnet producer can assist in magnetic circuit analysis which will determine this actual operating flux. From the analysis, a method of test shall be chosen which will cause the magnet being tested to operate at levels which duplicate the performance in the final circuit. The magnet user and supplier shall agree upon a reference magnet to be used to calibrate the test equipment. The acceptance limits shall be agreeable to both manufacturer and user. The acceptability of a magnet shall be judged solely by a comparison with the reference magnet tested in an identical manner. 9.2 Visual Characteristics: The recommended procedure for establishing acceptable levels for visual characteristics is for manufacturer and user to prepare a mutually agreed upon set of go/no-go standards or sample boards. In the absence in such a set of standards or other descriptions of acceptable criteria, the guidelines set forth in each individual section apply.